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George Louca is expected to appear in the Kempton Park Magistrate's Court on Monday in connection with the murder of Teazers boss Lolly Jackson.
Louca returned to South Africa on Sunday morning after losing his final appeal in the Cypriot Supreme Court, the last of several attempts to evade extradition.
Louca fled South Africa after the murder of strip club boss Jackson at a house in Edenglen on May 3, 2010. He allegedly phoned Gauteng crime intelligence boss Joey Mabasa and confessed to killing Jackson shortly after the murder.
Lieutenant-General Solomon Makgale said on Sunday that the Hawks were investigating a number of other cases to which Louca could possibly be linked.
Louca previously told the Sunday Times that he did not believe he would be granted a fair trial. - Sapa