The 45-year-old singer and Jwan Yosef arrived on the Caribbean island on Monday with supplies for residents after Hurricane Maria devastated the land mass, leaving its 3.4 million islanders without power and thousands homeless.
Jwan posted a selfie of the pair in front of the plane and added the caption: "We flew this @fedex cargo plane with aid to the western part of Puerto Rico THANK U @fedex for joining us in this alliance #hurricanemaria #puertorico (sic)"
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Just last week, Ricky, who was born in the country's capital city San Juan, flew to the island with fellow performers Luis Fonsi, Nicky Jam, and Chayanne.
Luis posted a picture of the quartet in the jet on his Instagram account and wrote: "United more than ever for Puerto Rico (sic)"
Ricky has raised nearly $3 million for the relief effort in Puerto Rico, where residents are in need of food, fuel and water.
The official death toll from the natural disaster stands at 36, but it is expected to rise.
Last week, Bethenny Frankel chartered three planes filled with cash, food and medical supplies to Puerto Rico to help those affected by Maria.
#WorkingForPuertoRico this warehouse was FULL a few days ago. All the supplies has been transported to PR to help those who are in desperate need. Help me fill it up again by donating at www.bstrongdeliverygood.org/BStrong #100percent #thisisacrisis #wedobetter #BStrong @globalempowermentmission
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For the return journey, she planned to fill the empty airplanes full of Puerto Rico cancer patients to bring them back to the US for treatment.
In a caption attached to a number of pictures of the donations, she wrote: "Here we are at our headquarters organizing and loading the truck for the planes heading to PR from Miami, Fort Lauderdale and NYC. Filling 3 planes with supplies, suitcases full of cash cards, pediatric supplies, insulin, hygiene products, medics, non perishable food, Rescue Warrior nurses, EMTs, combat medics. We will return these planes full of PR cancer patients, diabetics and people that are dying. Please donate to bstrongdelivergood.org to help me with these efforts.